A sandwich compound is an organic substance that consists of two arene (ring) ligands and a metal connected by haptic, covalent connections. Substituted derivatives and heterocyclic derivatives of arenes all share the formula CnHn. It is called "sandwiched" because the metal is often sandwiched between the two rings. The metallocenes are a unique subclass of sandwich complexes. In a 1956 paper, J. D. Dunitz, L. E. Orgel, and R. A. Rich established the structure of ferrocene using X-ray crystallography, and used this information to coin the phrase "sandwich compound" in organometallic nomenclature. Robert Burns Woodward and Ernst Otto Fischer each independently predicted the proper structure some years prior, which calls for the molecule to include one iron atom squished between two parallel cyclopentadienyl rings.
Stanislaw Dzwigaj
Sorbonne University, France
Dai Yeun Jeong
Asia Climate Change Education Center, Korea, Republic of
Enrico Paris
CREA-IT & DIAEE, Italy
Hanna Kierzkowska Pawlak
Lodz University of Technology, Poland
Ling Yin
Cornell University, United States
Tsitsishvili Vladimer
Petre Melikishvili Institute of Physical and Organic Chemistry at the Tbilisi State University, Georgia
Rafia Ahmad
King Abdullah University of Science and Technology, Saudi Arabia
Eun Han Lee
Korea Institute of Energy Research, Korea, Republic of
Neul Ha
Sungkyunkwan University, Korea, Republic of
Shailza Sharma
RMIT University, AustraliaSubmit your abstract Today
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