Using a light pointer and a flat, unstructured silicon electrode modified with an organic self-assembled monolayer (SAM) with a single ohmic contact, light-activated electrochemistry, or LAE, can spatially resolve electrochemistry. The semiconducting electrode must be biassed into depletion at the redox potential of the species of interest,
the redox couple must be covalently attached to the electrode, and the silicon must be protected from oxidation with a self-assembled monolayer (SAM). These three conditions are necessary for light-activated electrochemistry. Faradic electrochemistry at a monolayer protected monolithic silicon electrode can be "turned on" at any location with micron scale resolution by simply illuminating that area with light, according to the powerful concept of light-activated electrochemistry.
Stanislaw Dzwigaj
Sorbonne University, France
Dai Yeun Jeong
Asia Climate Change Education Center, Korea, Republic of
Sergey Suchkov
N.D. Zelinskii Institute for Organic Chemistry of the Russian Academy of Sciences, Russian Federation
Enrico Paris
CREA-IT & DIAEE, Italy
Rabeharitsara Andry Tahina
GPCI-ESPA Antananarivo University, Madagascar
Jiri Dedecek
J Heyrovsky Institute of Physical Chemistry , Czech Republic
Uday Som
Research and Development Engineer, Japan
Vladimir G Chigrinov
Hong Kong University of Science and Technology, Russian Federation
Osman Adiguzel
Firat University, TurkeySubmit your abstract Today
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