The glycosidic C—C bond's construction is used by the majority of techniques. These C-glycosylation techniques are grouped here according to the glycosyl donor precursors that are often utilised in the synthesis of O-glycosides and are simple for non-experts to obtain. The glycosyl halides, glycals, sugar acetates, lactones, lactones, lactones, 1,2-anhydro sugars, thioglycosides/sulfoxides/sulfones, selenoglycosides/telluroglycosides, methyl glycosides, and glycosyl imidates/phosphates are some of these substances. Glycosyl electrophilic/cationic species, anionic species, radical species, or transition-metal complexes can all play a role in C-glycosylation processes in terms of their underlying mechanisms, which are covered as subcategories under each kind of sugar precursor. The Claisen, Ramberg-Bäcklund, and 1,2-Wittig rearrangements, which frequently include coordinated pathways, are only a few examples of intramolecular rearrangements. These rearrangements also fall under the category of C-glycosylations. The development of pyranoside/furanoside rings following the creation of the C-glycosylations provides an alternative to the C-glycosylations.
Stanislaw Dzwigaj
Sorbonne University, France
Thomas J Webster
Brown University, United States
Dai Yeun Jeong
Asia Climate Change Education Center, Korea, Republic of
Sergey Suchkov
N.D. Zelinskii Institute for Organic Chemistry of the Russian Academy of Sciences, Russian Federation
Jiri Dedecek
J Heyrovsky Institute of Physical Chemistry , Czech Republic
Vladimir G Chigrinov
Hong Kong University of Science and Technology, Russian Federation
Osman Adiguzel
Firat University, Turkey
Uday Som
Shizuoka University, Japan
Rabeharitsara Andry Tahina
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