When one of the reaction products also serves as a catalyst for a different chemical process, such as a linked reaction, the chemical reaction is said to be autocatalytic. An autocatalytic reaction is one such reaction. A group of chemical processes is considered to be "collectively autocatalytic" if many of them result in catalysts for enough of the other reactions that the complete group of reactions can function on their own in the presence of energy and food molecules. The entropy of a physical or chemical system and its surroundings (a closed system), according to the second rule of thermodynamics, must rise with time. When left to their own devices, systems grow more chaotic, and the organised energy of a system like uniform motion gradually degrades to the haphazard movement of particles in a heated environment. However, there are several occasions when emergent or ordered physical systems arise on their own. When compared to the random motion of the air molecules in a closed room, for instance, hurricanes exhibit a relatively organised vortex motion despite the destruction they create. The order produced by chemical systems is even more amazing, with the order connected to life being the most striking. This is in line with the Second Law, which states that the overall disorder of a system and its surroundings must progressively worsen over time. An even greater lack of order in the system's surrounds can be used to generate order within the system. In the hurricane example, storms are created by uneven heating of the atmosphere. Thus, thermal equilibrium is distant from the Earth's atmosphere. The Earth's atmosphere becomes more ordered, but at the price of the sun's order. As the sun matures and emits material and light to the rest of the cosmos, it becomes more disorganised. Despite the fact that the earth produces orderly hurricanes, the overall chaos of the sun and the planets worsens.
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Vladislav Sadykov, Boreskov Institute of Catalysis, Russian Federation
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