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L. A. Voropanova

Title: The use of industrial wastes as catalysts of oxidative processes

L. A. Voropanova

North-Caucasian Mining-Metallurgical Institute, Russia


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The use of industrial waste to clean gases from environmentally hazardous components not only solves the problem of their utilization, but also creates waste-free, efficient and economical technologies for processing raw materials, solving the problems of their integrated use.
A high activity of anode slime of electrochemical plants in the processes of catalytic oxidation of carbon monoxide and hydrocarbons was established. Anodic sludge has a complex physicochemical structure and composition corresponding to oxides and hydroxides in higher oxidation states, compounds of transition metals with variable valency crystallizing in structures having catalytic activity in oxidation reactions of carbon monoxide and hydrocarbons.
It has been established that sorbents saturated with non-ferrous metal ions extracted from aqueous solutions of their salts possess catalytic properties in oxidation reactions. The high efficiency of the use of bentonite clay containing metal ions, including those used in wastewater treatment cycles, for cleaning the gaseous phase from hydrocarbons (up to 75%) is shown.
A method is proposed for using dehydrochlorinated PVC waste to purify waste gases from hydrocarbons to 67% and CO to 19%, while the problem of decontamination of waste
The possibility of using waste metal processing shops in gas cleaning systems is shown.
The options for mutual cleaning of air and water basins in the zone of influence of industrial enterprises are considered. Using the example of the use of an organo-aluminum coagulant and bentonite clays, the effectiveness of such a process is shown.