HYBRID EVENT: You can participate in person at Rome, Italy or Virtually from your home or work.
Stanislaw Dzwigaj, Speaker at Catalysis Conference
Sorbonne University, France
Title : CO2-assisted dehydrogenation of propane to propene over Zn-BEA zeolites: Impact of acid–base characteristics on catalytic performance

Abstract:

Research results about the influence of BEA zeolite preliminary dealumination on the acid–base characteristics and catalytic performance of 1% Zn-BEA compositions in propane dehydrogenation with CO2 are presented. The catalyst samples, prepared through a two-step post-synthesis procedure involving partial or complete dealumination of the BEA specimen followed by the introduction of Zn2+ cations into the T-positions of the zeolite framework, were characterized using XRD, XPS, MAS NMR, SEM/EDS, low-temperature N2 ad/desorption, C3H8/C3H6 (CO2, NH3)-TPD, TPO-O2, and FTIR-Py techniques. Full dealumination resulted in the development of a mesoporous structure and specific surface area (BET) with a twofold decrease in the total acidity and basicity of Zn-BEA, and the formation of Lewis acid sites and basic sites of predominantly medium strength, as well as the removal of Brønsted acid sites from the surface. In the presence of the ZnSiBEA catalyst, which had the lowest total acidity and basicity, the obtained selectivity of 86–94% and yield of 30–33% for propene (at 923 K) exceeded the values for ZnAlSiBEA and ZnAlBEA. The results of propane dehydrogenation with/without carbon dioxide showed the advantages of producing the target olefin in the presence of CO2 using Zn-BEA catalysts

Audience Take Away Notes:

  • The audience will be able to understand as control of preparation of catalyst systems. 
  • They will see that catalytic activity depend on dispersion of metal in the framework of zeolite.
  • The researchers will be able, after my talk, do their own catalyst preparation using similar method

Biography:

Professor Stanislaw Dzwigaj received his PhD degree in 1982 in Jerzy Haber Institute of Catalysis and Surface Chemistry, Krakow (Poland). After two years of postdoctoral stay at the Laboratoire de Réactivité de Surface Université P. et M. Curie (Paris) he obtained in 1990 a position of contracted researcher in the same Laboratory devoted to surface reactivity in relation to catalysis phenomena. Then, in 2008 he obtained permanent position in CNRS as a researcher. On February 19, 2014 for outstanding scientific achievements, he received the title of professor.  His published work includes more than 180 papers published in reputable international journals.

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